• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a process for removing impurities from triglyceride oils in which before the removal is effected the level of hydratable phosphatide is increased. The phosphatide together with the impurities can be removed from the oil by any suitable degumming process. Impurities which are removed by the process of the invention include iron, non-hydratable phosphatides, waxes, sterolglucosides, etc.
    公开号:SU841596A3
    申请号:SU772522503
    申请日:1977-09-09
    公开日:1981-06-23
    发明作者:Корнелис Зегерс Якобус
    申请人:Юнилевер Н.В. (Фирма)；
    IPC主号:
    专利说明:

    The invention relates to the food industry, in particular to methods for the purification of triglyceride oils. Untreated or incompletely purified oils contain, besides triglycerides of fatty acids, various mixtures of sugar, wax, beams, free fatty acids, phosphatides, metals, etc. Depending on the subsequent use of the oils., A number of these components must be removed. A particularly important group of impurities are phosphatides, hydratiadic, and non-hydrating. The former are easily removed from the oil by hydration with water or steam, usually at a high temperature, when the phosphatides are delgiots insoluble in oil and can be separated, and lecithin is obtained. Non-hydrating phosphatides are difficult to separate, since their conversion to a hydrating form requires treatment with strong acids and alkalis. Sometimes alkaline neutralization is combined with treatment with phosphoric acid to facilitate the removal of non-hydrating phosphatides. But this requires additional alkali consumption to neutralize phosphoric acid, and calcium and magnesium ions, isolated from non-hydrating phosphatides, form insoluble phosphate compounds and, after settling, entrain oil. In addition, phosphatides, sugars, glycerin, and other impurities are transferred to soap stock, which causes difficulties with. decomposing soaps. After decomposition, they occur in acidic wastewater. The closest to the invention is a method of purifying oils using acid anhydride as a cleaning agent, which removes impurities such as sugars, sterols, proteins, glycerols, wax, etc. that are non-hydrating from phosphatides. are removed at the stage of alkaline refining together with soap stock, where they form difficult-to-decompose emulsions, which leads to a high loss of oil fatty acids. Transitioning substances into acidic drains are discharged into the sewer system. The purpose of the invention is to increase the completeness of oil purification. The goal is achieved by using hydrating phosphatide as a cleaning agent, 0.01-5 wt.%. preferably 0.1-2%. In addition, it is advisable to use phosphatide allocated by water hydration of the oils, as well as a fraction of hydrating phosphatide. Phosphatide along with impurities are removed by any of the known techniques, for example, hydration with water or steam and centrifugation with the addition of electrolytes, for example dilute or concentrated acids, acid or alkali anhydrides, salts and / or surface active substances. As hydrating phosphide, it is preferable to use phosphatides obtained by treating vegetable oils, for example soybean, peanut, sunflower, rapeseed, cottonseed, etc., but they can also be obtained from other sources, for example, from egg yolk or synthesis. Before adding phosphatides to the oil to be cleaned, it is advisable to dry under reduced pressure. In addition, parts of but hydrolyzed, hydroxylated and / or acylated lecithins can be used, as well as fractions obtained by fractionating phosphatides with a solvent or mixture of solvents. The method is carried out as follows. These phosphatides in the amount of 0.01-5% are introduced into the oil to be purified. The phosphatides are then removed from the oil by one of the known techniques. It is preferable to mix the oil at 65-9 ° C with a concentrated acid or acid anhydride having a pH of at least 0.5 with an unidirectional aqueous solution. Then, 0.2–5 wt.% Of water is dispersed, and before separating. The mixture of oil, water and acid (or anhydride) is kept for at least 5 minutes at a temperature below, for example, 2. containing at least 25% acid. A suitable amount of citric acid is 0.001-5% (dry basis). Instead of hydration, phosphatides can be removed by ultrafiltration or membrane filtration. The method allows the removal of not only hydrating, but also non-hydrating phosphatides from oil. Sugars, sterols, glycerin, proteins, waxes, etc. Removed from the oil, can be used, for example, in the manufacture of animal feed. Alkaline neutralization can be eliminated and fatty acids removed by distillation. In addition, heavy metals, such as iron, are removed from the oil. These have a detrimental effect on the stability of the oil. Usually, the removal of oils with strong acids and bleaching earth is used to remove them, which leads to significant oil blemishes and difficulties in dumping the treated earth. The proposed method gives especially good results when processing oils that do not contain or contain scarlet amounts of hydrating and noticeable amounts of non-hydrating phosphatides, for example rapeseed or sunflower oil. Preliminary addition of hydrating phosphatides leads to a decrease in the required amount of acid or anhydrides, which, in addition to their economy, leads to an improvement in the quality of phosphatides. If, however, oils containing a small amount of non-hydrating phosphatides or not containing them at all, such as palm, palm and coconut oils, are to be cleaned, it is advisable to remove the phosphatides by ordinary water hydration. Example 1. To two batches of soybean oil samples, from which hydrating phosphatides are previously removed by steam treatment and sediment separation and which contain only non-hydrating phosphatides as phosphatidic acid, are added after heating to 70 ° C. Different amounts of dry hydrating phosphatides or lecithin obtained by steam treatment. One sample contains 0.0255, and the other, 0.0183% of non-hydrating phosphatides. A solution of citric acid in water (1: 1) is then added and, after stirring, cooled to give 1.5% water and allowed to stand for 60 minutes with slight overmixing. The precipitate is removed by centrifugation. Table 1 presents the conditions of the experiments. Table 1 0.0183
    Continued table. one
    Example 2. To a liquid fraction of palm oil containing 0.0004% phosphorus and 0.001% iron, add 0.3% of hydrating phosphatides, then phosphatides are removed by the method 5 of Example 1. After treatment, the iron content is reduced to 0.00019%. Example 3. To two samples of crude rapeseed oil (500 g each) are added respectively
    Q 0.3 and 0.9% hydrates of phosphatides. Then the oils are heated up to, mixed with 0.3% solution-1 (1) solution of monitric acid and stirred for 15 minutes. After that, the oils are cooled until 5% water is added, stirring for 1 h.
     and the aqueous precipitate is separated by centrifugation. The resulting oils are analyzed for phosphorus, calcium, and magnesium.
    Table 2 shows the dependence
    0 degree of purification of the amount of added phosphatide.
    table 2
    Experiments show that for samples of the first batch, the average phosphorus content can be reduced to 0.0021%, while preliminary addition of 0.25% of lecithin reduces this indicator to 0.0016%. For samples of the second batch, these figures are respectively 0.0036 and 0.00119% with the addition of 0.5% lecithin. The amount of acid needed is drastically reduced to achieve the same effect.
    Izves0 0131 0,0113 0,0021 tny 0,0026 0,0014 0,0003
    Prev0, 0017 0.0004 0.0001 Generated 0.3 0.0008 0.000090.00003
    0.9
    Example 4. Soybean oil, from
    5 of which most of the hydratable phosphatides are removed by the addition of water and centrifugation, and which has a residual phosphorus content of 0.0078%, are mixed with
    0 0.3% alcohol-soluble fraction of soy lecithin. Then add 0.1 of a solution of citric acid (1g1), cool the mixture until, add 2.5% water and, after gentle stirring
    5 for 2 h, centrifuged. Phosphorus is not detected in the resulting oil. When processed without adding lecithin, 0.0021% phosphorus remains in the oil. Example 5. Soybean oil with a residual phosphorus content of 0.001%
    权利要求:
    Claims (3)
    [1]
    0 mixed with 0.3% lecithin, hydrolyzed with enzymes. Then (a 0.1% solution of citric acid (1: 1), 2.5% of water was added and, after a gentle stirring for 2 hours, the mixture was centrifuged. In the resulting oil, no phosphorus was detected. When treated without adding lecithin, the oil contains 0, 0022%. Example 6. Crude sunflower oil with a phosphorus content of 0.0065 and socks 0.1445% is mixed with 0.3% lecithin. Then 0.3% 50% citric acid solution is added. The mixture is cooled until added 2.5% water, mixed gently for 1 hour and centrifuged. In the resulting purified oil, phosphorus is not detected, and the content The wax content is 0.0087%. The oil treated in the same way, but without adding lecithin, contains 0.0011% phosphorus and 0.0491% waxes. Example 7. Crude palm oil containing 0.0007% iron is mixed at 70s 0.3% lecithin, cooled before and 2.5% water is added. After the mixture is stirred gently for 2 hours, the mixture is centrifuged. The purified oil contains 0.00027 iron. When adding 1.0% lecithin, the treated oil contains 0.00018% gland. Example 8. Soybean oil after hydration with a phosphorus content of 0.0097% is mixed with 3% of commercial lecithin. After stirring for 15 minutes, 0.15% acetic anhydride is added, then again, after stirring for 15 minutes, 1.5% water and again after stirring for 15 minutes, the mixture is centrifuged at. The resulting oil was 0.00058% phosphorus. Without lecithin, the treatment gives an oil with a phosphorus content of 0.0073%. Claim 1. Technique for purifying triglyceride oils by adding a cleansing agent and separating it together with impurities by one of the known techniques, characterized in that, in order to improve the completeness of the cleansing of oils, hydrating phosphatid is used as a cleansing agent, taken in an amount of 0.01. -5 wt.%, Preferably 0.1 to 2%.
    [2]
    2. The method according to claim 1, is also distinguished by the fact that phosphatide is used, which is isolated by aqueous hydration of oils.
    [3]
    3. The method according to claim 1, characterized in that the hydrating lecithin fraction is used. Sources of information taken into account in the examination 1. US patent number 2782216, CL 260-424, published. 1957.
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    同族专利:
    公开号 | 公开日
    FI62135B|1982-07-30|
    GB1585166A|1981-02-25|
    DE2740752C3|1980-05-14|
    AR214088A1|1979-04-30|
    NL7709915A|1978-03-14|
    PT67020A|1977-10-01|
    YU213077A|1982-08-31|
    NO773123L|1978-03-13|
    ZA775440B|1979-04-25|
    YU39818B|1985-04-30|
    DK144381B|1982-03-01|
    SE7710167L|1978-03-11|
    DK144381C|1982-09-13|
    ES462266A1|1978-05-16|
    IE45483B1|1982-09-08|
    MY8400097A|1984-12-31|
    FR2364267B1|1982-07-16|
    NL173283B|1983-08-01|
    BE858585A|1978-03-09|
    DD132877A5|1978-11-15|
    CH630403A5|1982-06-15|
    LU78107A1|1978-06-01|
    PT67020B|1979-09-12|
    US4162260A|1979-07-24|
    RO75740A|1981-02-28|
    UA8256A1|1996-03-29|
    IN147013B|1979-10-20|
    FI772645A|1978-03-11|
    DK399777A|1978-03-11|
    SE426248B|1982-12-20|
    ATA643477A|1980-12-15|
    CS214879B2|1982-06-25|
    PL105753B1|1979-10-31|
    TR19416A|1979-03-19|
    PL200751A1|1978-05-08|
    GR64061B|1980-01-21|
    DE2740752A1|1978-03-16|
    JPS5335709A|1978-04-03|
    AT363154B|1981-07-10|
    IT1117117B|1986-02-10|
    NO147605B|1983-01-31|
    NO147605C|1983-05-18|
    FR2364267A1|1978-04-07|
    NL173283C|1984-01-02|
    DE2740752B2|1979-09-06|
    BR7706018A|1978-06-27|
    FI62135C|1982-11-10|
    AU2858477A|1979-03-15|
    IE45483L|1978-03-10|
    CA1095530A|1981-02-10|
    AU510475B2|1980-06-26|
    JPS5933159B2|1984-08-14|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3134794A|1955-03-07|1964-05-26|Staley Mfg Co A E|Method for continuous degumming of vegetable oil|
    GB1541017A|1975-03-10|1979-02-21|Unilever Ltd|Degumming process for triglyceride oils|US4399224A|1981-07-13|1983-08-16|A. E. Staley Manufacturing Company|Enzymatically treated phosphatides|
    US4609500A|1981-10-15|1986-09-02|Cpc International Inc.|Refining of oil and product thereof|
    WO1983003843A1|1982-04-21|1983-11-10|Unilever Nv|Refining|
    GB8307594D0|1983-03-18|1983-04-27|Unilever Plc|Triglyceride oils|
    GB8423229D0|1984-09-14|1984-10-17|Unilever Plc|Treating triglyceride oil|
    GB8506907D0|1985-03-18|1985-04-24|Safinco Coordination Centre Nv|Removal of non-hydratable phoshatides from vegetable oils|
    JP2524720B2|1986-12-02|1996-08-14|昭和産業株式会社|Degumming method of fats and oils|
    JPS648296U|1987-07-03|1989-01-18|
    GB8814732D0|1988-06-21|1988-07-27|Unilever Plc|Method of refining clyceride oils|
    US5286886A|1988-06-21|1994-02-15|Van Den Bergh Foods Co., Division Of Conopco, Inc.|Method of refining glyceride oils|
    BE1001858A3|1988-06-29|1990-03-20|Schelde Delta Bv Ba|METHOD FOR REFINING OILS|
    JPH0268342U|1988-11-15|1990-05-23|
    US5348984A|1993-01-28|1994-09-20|Sealed Air Corporation|Expandable composition and process for extruded thermoplastic foams|
    EP1417288B1|2001-07-23|2018-08-29|Cargill, Incorporated|Method and apparatus for processing vegetable oils|
    US20110047866A1|2009-08-31|2011-03-03|Conocophillips Company|Removal of impurities from oils and/or fats|
    AU2013364289B2|2012-12-19|2016-07-14|Buckman Laboratories International, Inc.|Methods and systems for bio-oil recovery and separation aids therefor|
    CN109259237B|2018-10-22|2021-11-09|辽渔南极磷虾科技发展有限公司|high-EPA/DHA type antarctic krill oil phospholipid pill and preparation method thereof|
    CN109198042B|2018-10-22|2021-10-08|辽渔南极磷虾科技发展有限公司|high-EPA/DHA type antarctic krill oil phospholipid oral liquid and preparation method thereof|
    CN109439430B|2018-10-22|2021-10-08|辽渔南极磷虾科技发展有限公司|Euphausia superba oil refining method|
    WO2021247274A1|2020-05-30|2021-12-09|Cargill, Incorporated|Process for making oil-free compositions comprising phospholipds|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    GB37643/76A|GB1585166A|1976-09-10|1976-09-10|Oil purification by adding hydratable phosphatides|
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